Rational Design of Highly Activating Ligands for Cu-Based Atom Transfer Radical Polymerization
نویسندگان
چکیده
منابع مشابه
Modification of Polyvinyl Alcohol via Atom Transfer Radical Polymerization for Targeted Drug Delivery Applications
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............................................................................................................................. iii Acknowledgments............................................................................................................... v Table of
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The kinetics of activation of RX by a Cu(I) complex has been investigated in MeCN both in the absence and presence of halide ions. The system Cu(I)/L/X(-) (L = Me(6)TREN) is mainly composed of Cu(I)L(+), XCu(I)L and Cu(I)X(2)(-), but only Cu(I)L(+) is found to be an active catalyst reacting with RX.
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ژورنال
عنوان ژورنال: The Journal of Organic Chemistry
سال: 2019
ISSN: 0022-3263,1520-6904
DOI: 10.1021/acs.joc.9b02915